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- W1998496660 abstract "Curves of instantaneous copolymer composition vs fractional conversion (θ) have been calculated for the copolymerization of N-vinyl-2-pyrrolidone (VP) with n-butyl acrylate (BA). These systems display compositional heterogeneity, the onset of which occurs at values of θ that are lower the higher the content of VP in the feed. Low conversion samples of poly(VP-co-BA) have been mixed in proportions so as to simulate the overall composition of material present cumulatively at different stages of an actual copolymerization. These blends have been examined with regard to their light transmission and glass transition behaviour. The findings accord with the compositional heterogeneity predicted from the calculated curves. The curves also account satisfactorily for the visually assessed clarity, translucency or opacity of copolymers prepared in bulk by γ-irradiation over the interval θ = 0.016−0.998." @default.
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- W1998496660 date "1991-01-01" @default.
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- W1998496660 title "Polymer-polymer miscibility during copolymerization" @default.
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- W1998496660 doi "https://doi.org/10.1016/0014-3057(91)90073-w" @default.
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