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- W1998498001 abstract "The effects of various alkyl, phenyl and fluorinated bonded phases on the selectivity towards stereoisomers of polystyrene oligomers using acetonitrile—water gradients in reversed-phase high-performance liquid chromatography were compared. All alkyl phases tested, from a trimethylsilyl (C1) to an octadecylsilyl (C18) bonded phase, separated stereoisomers. An increased chain length of the alkyl ligand made only a minor contribution to the resolution. Bonded phases of ethylphenyl and isopropylphenyl, capped with trimethylsilane or non-capped, produced only oligomer separation. Similarly, a synthesized fluorodecyl bonded phase (RPF-10) only gave oligomer separation; however, the corresponding capped fluorinated phase provided some stereoisomer separation. In contrast, commercially available capped and non-capped fluorodecyl phases provided even less isomer selectivity." @default.
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- W1998498001 date "1984-01-01" @default.
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- W1998498001 title "Stationary phase effects in reversed-phase high-performance liquid chromatographic fractionations of stereoisomers of styrene oligomers" @default.
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- W1998498001 doi "https://doi.org/10.1016/s0021-9673(01)97849-5" @default.
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