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• W1998503802 endingPage "259" @default.
• W1998503802 startingPage "253" @default.
• W1998503802 abstract "The CuI complex Cu(CH3CN)4+PF6− chemoselectively abstracts phosphine from Cp(CO)(PPh3FeCOCH3 and produces Cp(CO)2FeCH3 in good yield. No evidence for electrophilic CuI coordinating the acetyl ligand on Cp(CO)(L)FeCOCH3 (L = CO, PPh3), however, was obtained Reactions of CuI and Cp(CO)(PPh3)FeCH3, with and without the presence of CO, also were examined. With CO, this methyl complex first gives its acetyl derivative Cp(CO)(PPh3)FeCOCH3 (1 atm CO in CH2Cl2 solution, 5 min), and after excess CO is removed (it otherwise blocks further reaction), Cp(CO)2FeCH3 forms." @default.
• W1998503802 created "2016-06-24" @default.
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• W1998503802 creator A5039949127 @default.
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• W1998503802 date "1986-07-01" @default.
• W1998503802 modified "2023-09-27" @default.
• W1998503802 title "Copper(I) as a phosphine abstractor from (η-C5H5)(CO)(PPh3)FeCOCH3" @default.
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• W1998503802 doi "https://doi.org/10.1016/s0022-328x(00)99542-1" @default.
• W1998503802 hasPublicationYear "1986" @default.
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