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• W1998558508 abstract "An automatic Sievert's apparatus equipped with an in situ temperature-programmed desorption (TPD) analyzer was constructed to study the cyclic hydrogenation stability of the Ti25V35Cr40 alloy with minor impurities in H2 gas. A mass spectrometer (MS) was used to examine the interactions between the impurities and the as-cycled Ti25V35Cr40 hydrides. The reactivity of the specimen with hydrogen decreased significantly. The hydrogen content of the specimen decreased severely from 0.73 H/M to 0 H/M after 82 cycles. The combined results obtained from in situ TPD-MS and the pressure–composition (P–C) isotherm curves revealed that degradation in the hydrogenation processes resulted from the formation of shield films composed of a mixture of H2S, O2, CO, and CH4 species present in the H2 gas source. A reactivation start-up temperature of 170 °C to break the shield film was found using the in situ TPD and TPD-MS techniques developed in this study." @default.
• W1998558508 created "2016-06-24" @default.
• W1998558508 creator A5030613500 @default.
• W1998558508 creator A5040527746 @default.
• W1998558508 date "2015-03-01" @default.
• W1998558508 modified "2023-09-25" @default.
• W1998558508 title "Passivation and reactivation of Ti25V35Cr40 hydrides by cycling with impure hydrogen gas" @default.
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• W1998558508 doi "https://doi.org/10.1016/j.ijhydene.2015.01.047" @default.
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