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- W1998581434 abstract "Deformed Chiral [n]Metacyclophanes The new dithiametacyclophane 3c and the thiaazametacyclophanes 6a, b are chiral, but do not contain chirality centres. They are obtained by cyclization of 1,3‐propanedithiol ( 2 ), or of the thiaza precursors 5a, b , with the bis(bromomethyl) compounds 1, 4a, b. The dynamic behaviour of the aliphatic chains in 3c , and 6a, b (flipping/rotation) have been studied by dynamic NMR. X‐ray analyses of 3c and 6a document the out‐of‐plane deformation of the boat‐shaped benzene ring. The circular dichroism of enantiomer‐enriched 3c is reported." @default.
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- W1998581434 date "1994-04-01" @default.
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- W1998581434 title "Deformierte chirale [n]Metacyclophane" @default.
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- W1998581434 doi "https://doi.org/10.1002/cber.19941270427" @default.
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