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• W1998583899 abstract "The present work demonstrates a systematic approach for the synthesis of pure kesterite-phase Cu2ZnSnS4 (CZTS) nanocrystals with a uniform size distribution by a one-step, thioglycolic acid (TGA)-assisted hydrothermal route. The formation mechanism and the role of TGA in the formation of CZTS compound were thoroughly studied. It has been found that TGA interacted with Cu(2+) to form Cu(+) at the initial reaction stage and controlled the crystal-growth of CZTS nanocrystals during the hydrothermal reaction. The consequence of the reduction of Cu(2+) to Cu(+) led to the formation Cu2- x S nuclei, which acted as the crystal framework for the formation of CZTS compound. CZTS was formed by the diffusion of Zn(2+) and Sn(4+) cations to the lattice of Cu2- x S during the hydrothermal reaction. The as-synthesized CZTS nanocrystals exhibited strong light absorption over the range of wavelength beyond 1000 nm. The band gap of the material was determined to be 1.51 eV, which is optimal for application in photoelectric energy conversion device." @default.
• W1998583899 created "2016-06-24" @default.
• W1998583899 creator A5012817120 @default.
• W1998583899 creator A5021226984 @default.
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• W1998583899 date "2014-04-09" @default.
• W1998583899 modified "2023-10-02" @default.
• W1998583899 title "One-step synthesis of high quality kesterite Cu₂ZnSnS₄ nanocrystals – a hydrothermal approach" @default.
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• W1998583899 doi "https://doi.org/10.3762/bjnano.5.51" @default.
• W1998583899 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3999833" @default.
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