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• W1998606827 abstract "To understand the electron irradiation effects on polymers, a polyesterurethane (ESPU) was irradiated by a 200keV electron beam perpendicular to the surface under a vacuum of 0.04Torr with electron fluxes of 0.25–1.25×1013s−1 on the irradiated zone. To perform a study of ESPU degradation versus the electron's penetration depth, a stratified structure was made with seventeen 30-μm-thick films. The irradiation was performed at both room temperature (293K) and 77K. The applied fluence was in the range of 1014–1017cm−2. Chemical transformations, such as degradation and oxidation, are studied by FTIR, by following NH and OH bond evolution, and by UV spectroscopy, by following the absorbance shift towards the visible region. These effects are analyzed versus depth, fluence and electron flux. Structural transformations are also characterized by GPC for soluble samples. An increase of crosslinking rate of the polymer is observed and analyzed." @default.
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• W1998606827 date "2001-06-01" @default.
• W1998606827 modified "2023-10-18" @default.
• W1998606827 title "Electron irradiation of polyesterurethane: study of chemical and structural modifications using FTIR, UV spectroscopy and GPC" @default.
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• W1998606827 doi "https://doi.org/10.1016/s1350-4487(01)00116-0" @default.
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