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- W1998647788 abstract "Abstract The retention indices, I, and the partial molar free energies of sorption, ΔG, have been determined for n-alkanes, aromatic hydrocarbons, aliphatic and aromatic amines and pyridine on three columns with hydrogenated Apiezon L containing equimolar quantities of KOH, KF and Na3PO4. It is shown that neither I nor ΔG of n-alkanes and aromatic hydrocarbons depends on the support treatment. The differences in the abilities of organic bases to undergo donor—acceptor interactions with KOH, KF and Na3PO4 under the conditions prevalent in gas chromatography have been estimated thermodynamically. It is shown that the contribution of the donor—acceptor interaction energy to the total partial molar free energy of sorption is the same for KOH and KF, but is higher for Na3PO4 and dependent on the type of organic base." @default.
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- W1998647788 date "1984-03-01" @default.
- W1998647788 modified "2023-09-27" @default.
- W1998647788 title "Thermodynamic distinction in donor-acceptor interactions of organic bases with KF and Na3PO4 on hydrogenated apiezon columns" @default.
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- W1998647788 doi "https://doi.org/10.1016/s0021-9673(01)99174-5" @default.
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