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• W1998693014 abstract "The reaction of salicylaldoxime (H2sao) with Mn(ClO4)2·6H2O, sodium 3,5-dinitrobenzoate and NEt4(OH) in MeOH/EtOH affords a MnIII hexanuclear compound [Mn6O2(sao)6(ArCO2)2(MeOH)2(EtOH)2(H2O)2] (ArCO2H = 3,5-dinitrobenzoic acid) (1). 1 contains [MnIII6(µ3-O)2]14+ core, with a known structural type in the family of Mn6 clusters. Temperature-dependent magnetic susceptibility study shows presence of predominant ferromagnetic interactions between MnIII ions. Alternating current (ac) susceptibility measurements reveal a frequency-dependent out-of-phase (χM′′) signal below 4 K, suggesting 1 to be a single-molecule magnet (SMM)." @default.
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• W1998693014 date "2010-07-01" @default.
• W1998693014 modified "2023-10-09" @default.
• W1998693014 title "A rare ferromagnetic manganese(III) hexanuclear cluster" @default.
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• W1998693014 doi "https://doi.org/10.1016/j.inoche.2010.04.003" @default.
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