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- W1998706714 abstract "Abstract β -Fluorosulphatoperfluoroalkyl radicals ( 3, 7 and 8 ) are obtained by the reaction of fluoroolefins (HFP trimer and dimer, and perfluoro4 4-dimethylpent-2-ene, respectively) with (FSO 3 ) 2 . The pure β -fluorosulphatotetrafluoroethylperfluorodiisopropylmethyl radical ( 3 ) has been isolated and converted to the perfluoroacetyldiisopropylmethyl radical ( 4 ) under the action of CsF. The reaction of radicals 3,7 and 8 with SbF 5 leads to the replacement of the FSO 3 group by a fluorine atom. The ability of the FSO 3 group in β -fluorosulphatoperfluoroalkyl radicals to play the role of a leaving group is explained by the stabilizing effect of the unshared electron on the adjacent carbocation centre." @default.
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- W1998706714 date "1996-10-01" @default.
- W1998706714 modified "2023-09-27" @default.
- W1998706714 title "Stable fluoroaliphatic radicals containing functional groups: Synthesis and reactivity" @default.
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- W1998706714 doi "https://doi.org/10.1016/s0022-1139(96)03491-4" @default.
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