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- W1998731664 abstract "The utility of phosphine-containing chiral ligands has been well established and a new type of axially chiral C(aryl)-N(amine) ligand is described. The authors use a simple procedure to access a family of these axially chiral ligands in racemic form. Next, they expertly employ a palladium source with existing chirality to generate diastereomers which are separable on a simple silica gel column. The palladium is then titrated off with ethylene diamine to yield the ligands optically resolved, both with >99% ee. Application of the ligands in the palladium-catalyzed allylic alkylation was then employed and all ligands gave ee values ≥89%." @default.
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- W1998731664 date "2006-12-01" @default.
- W1998731664 modified "2023-09-25" @default.
- W1998731664 title "Aminophosphines with Axial Chirality for Asymmetric Catalysis" @default.
- W1998731664 doi "https://doi.org/10.1055/s-2006-949502" @default.
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