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- W1998738316 abstract "MXnLm complexes of group VIII metals (X = halogen or hydride, L = phosphine or arsine, M = Ru, Rh) are efficient intromolecular hydrogen transfer catalysts of high selectivity from a secondary alcohol group to an α-ethylenic bond. The nature of the solvent is important. These reactions are used for the preparation of α-diketones and α-ketols from ethylenic α-diols. Some new preparations of complexes are described. Des complexes de métaux du groupe VIII du type MXnLm (X = halogénure ou hydrue, L = phosphine ou arsine, M = Ru, Rh) catalysent de façon sélective le transfert des atomes d'hydrogène de groupes alcools secondaires vers les liaisons éthyléniques situées en α. Le choix du solvant est important. Ces réactions ont été utilisées pour la préparation de dicétones-α et de cétol-α à partir de glycols-α éthyléniques. De nouvelles préparations de complexes sont décrites." @default.
- W1998738316 created "2016-06-24" @default.
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- W1998738316 date "1980-07-01" @default.
- W1998738316 modified "2023-09-27" @default.
- W1998738316 title "Transferts d'atomes d'hydrogene dans les alcools et glycols α-ethyleniques catalyses par des complexes de metaux du groupe VIII" @default.
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- W1998738316 doi "https://doi.org/10.1016/0304-5102(80)85035-8" @default.
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