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- W1998858507 abstract "The rates of reaction of l-cysteine, dl-penicillamine and dl-2-thiol-histidine with pyridoxal 5′-phosphate have been studied over the temperature range 10–38°. The apparent activation energies are, respectively, 11, 10 and 11 kcal at pH 7.8 and 12, 11 and 16 kcal at pH 6.3. The reaction of these thiol amino acids with the Schiff base which is formed between pyridoxal 5′-phosphate and l-glutamic acid is shown to be more rapid than the maximum rate of dissociation of the Schiff base. It is therefore concluded that these amino acids can attack the Schiff base directly, displacing the l-glutamic acid. This mechanism may be of significance in the inhibition of pyridoxal 5′-phosphate-dependent enzymes by thiol amino acids." @default.
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- W1998858507 date "1963-07-01" @default.
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- W1998858507 title "The reaction of thiol amino acids with pyridoxal 5′-phosphate in the absence and in the presence of l-glutamic acid" @default.
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- W1998858507 doi "https://doi.org/10.1016/0926-6569(63)90134-2" @default.
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