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- W1998889368 abstract "Abstract The effects of pyridine derivatives and some other nitrogenous ligands(including 2-methyl-pyridine, 3-methyl-pyridine, 4-methyl-pyridine. 2,6-dimethyl-pyridine, imidazole and azide) on the alkaline isomerization of ferric cytochrome c were studied by 1H-NMR. Bulky ligands like pyridine and its derivatives can facilitate the formation of alkaline form of cytochrome c and selectively stabilize one conformer of alkaline cytochrome c at enough concentration of such ligands. However, in the case of small ligands such as cyanide and azide, no such phenomena was observed. Being a ligand of medium size, imidazole has quite weak effect on alkaline isomerization of cytochrome c. It is interesting that 2-methyl-pyridine and 2,6-dimethyl-pyridine also have such effects on the alkaline isomerization of cytochrome c although they can not bind to the heme iron of cytochrome c due to the severe steric interactions between their methyl groups and the heme plane. This finding provides new evidence for the suggestion that the effects of pyridine and its derivatives on the alkaline isomerization of cytochrome c may not involve the binding of these exogenous ligands to the heme iron. The effect of 3-methyl-pyridine on the alkaline isomerization of cytochrome c was further quantitatively investigated by 2D-EXSY." @default.
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- W1998889368 date "1999-07-01" @default.
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- W1998889368 title "NMR Spectroscopic Studies of the Effects of Nitrogenous Ligands on the Alkaline Isomerization of Cytochrome C" @default.
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- W1998889368 doi "https://doi.org/10.1080/00387019909350003" @default.
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