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- W1998891812 abstract "Between S/P mole ratios of 0·75 and 3·50 in the phosphorus-sulphur system, quenching of melts gave completely amorphous compositions for S/P ratios of 1·0 and 1·25 (both viscous gums) and 3·0 and 3·5 (both brittle glasses). 31P nuclear-magnetic-resonance (n.m.r.) spectra of the viscous liquids (heated sufficiently to avoid line broadening) show that, for S/P = 1·0, 59 per cent of the total phosphorus and, for S/P = 1·25, 33 per cent of the total phosphorus is present as the P4S3 bird-cage molecule. On the other hand, viscosity data indicate that macromolecules are present in melts for which S/P > ca. 1·8. The rates of dissolution of the various crystalline, amorphous and partially amorphous phosphorus sulphides in n-butanol were measured and are interpreted on a per-unit-area basis. N.m.r. spectra of the solutions resulting from reaction of the butanol with the phosphorus sulphides show the presence of many phosphorus compounds." @default.
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- W1998891812 date "1989-07-01" @default.
- W1998891812 modified "2023-10-14" @default.
- W1998891812 title "4737718 Magnetic resonance imaging apparatus including a bird-cage r.f. coil" @default.
- W1998891812 doi "https://doi.org/10.1016/0730-725x(89)90502-x" @default.
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