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- W1998896288 abstract "Spiro-bis-dithiepins are synthesized via dehydrative ring expansion in α-hydroxyalkyl spiro-bis-dithianes. Atypical of spiranes possessing axial chirality, the two most stable conformers of substituted spiro-bis-dithiepin have virtually colinear double bonds; i.e., each enantiomer exists in a form of two energy degenerate syn and anti conformations. Because of the high polarizability of the vinyl sulfide moiety, spiro-bis-dithiepins bearing electron-withdrawing substituents offer access to two-state systems possessing large dipole moments, which can be modulated by conformational events." @default.
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- W1998896288 date "2006-10-01" @default.
- W1998896288 modified "2023-10-04" @default.
- W1998896288 title "Conformational Analysis of Spiro-bis-dithiepins: A Peculiar Case of Axial Chirality" @default.
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- W1998896288 doi "https://doi.org/10.1021/ol062172s" @default.
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