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- W1998897044 abstract "The nickel(II) complex with an open chain tetramine containing a piperazine fragment (1) displays an unusual resistance to demetallation in acidic solution and exhibits a lifetime of about five minutes in a solution 0.1 M in HClO4 and 7.0 M in NaClO4. Sluggishness with respect to the demetallation is ascribed to the occurrence of the boat-to-chair conformational conversion of the piperazine fragment, which implies the passage through the highly energetic half-boat transition state. The use of a high concentration of the inert electrolyte induces a ‘salting out’ effect on both thermodynamics (stability of metal complexes is enhanced) and kinetics (resistance to demetallation is increased)." @default.
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- W1998897044 date "2004-01-01" @default.
- W1998897044 modified "2023-10-18" @default.
- W1998897044 title "The influence of the boat-to-chair conversion on the demetallation of the nickel(ii) complex of an open-chain tetramine containing a piperazine fragment" @default.
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- W1998897044 doi "https://doi.org/10.1039/b312980b" @default.
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