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- W1998901097 abstract "Pentacarbonyleisen reagiert bei UV-Bestrahlung mit Tri(tert.-butyl)-, Tris(trimethylsilyl)-, Tris(trimethylgermyl)- bzw. Tris(trimethylstannyl)-phosphin unter Abspaltung eines CO-Liganden und Bildung entsprechender [Tris(triorganoelement-IVa)-phosphin]-tetracarbonyl-eisen-Komplexe. Dieselben Verbindungen entstehen auch unter Abspaltung von Pentacarbonyleisen aus Enneacarbonyldieisen und den genannten Tris(triorganoelement-IVa)-phosphinen. Die IR-, 1H-NMR- und 31P-NMR-spektroskopischen Daten der Komplexe werden mitgeteilt und diskutiert.Organometalphosphine Substituted Transition Metal Complexes, X. (Organometalphosphine)tetracarbonyliron ComplexesPentacarbonyliron reacts on u. v. irradiation with tri(tert-butyl)-, tris(trimethylsilyl)-, tris(tri-methylgermyl)-, and tris(trimethylstannyl)phosphine with displacement of one CO-ligand to give the corresponding tris[(triorganoelement-IVa)phosphine]tetracarbonyliron complexes. The same compounds can also be synthesized by elimination of pentacarbonyliron from enneacarbonyldiiron in the presence of the tris(triorganoelement-IVa)phosphines. The i. r., 1H n. m. r., and 31P n. m. r. spectroscopic data of the complexes are reported and discussed." @default.
- W1998901097 created "2016-06-24" @default.
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- W1998901097 date "1970-08-01" @default.
- W1998901097 modified "2023-09-27" @default.
- W1998901097 title "Organometallphosphin-substituierte Übergangsmetall-Komplexe, X. Organometallphosphin-tetracarbonyl-eisen-Komplexe" @default.
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- W1998901097 doi "https://doi.org/10.1002/cber.19701030806" @default.
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