FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1998921607> ?p ?o ?g. }

• W1998921607 endingPage "1840" @default.
• W1998921607 startingPage "1825" @default.
• W1998921607 abstract "The reactions of zinc and cadmium salts with 2,2′-biimidazole (H2biim) yielded a series of compounds in which the ligand is coordinated in the chelating bidentate mode. ZnCl2 and [Ag(H2biim)](NO3) in methanol in a 2:1 proportion produced Zn(H2biim)Cl2, in which the metal has a distorted tetrahedral coordination. A 1:2 ratio led to [Zn(H2biim)2(CH3OH)2](NO3)2, containing an octahedrally coordinated Zn(II) center with the O-bonded methanol ligands occupying trans positions. The corresponding [Cd(H2biim)2(CH3OH)2](NO3)2 compound was obtained from CdCl2. By starting with Cd(NO3)2 and Cd(ClO4)2 in aqueous media, the related octahedral bis-chelate compounds [Cd(H2biim)2(NO3)(H2O)](NO3) and Cd(H2biim)2(ClO4)2, respectively, were isolated, the apical positions being filled by perchlorate oxygens in the latter case. With Cd(BF4)2, the glass container participated in the reaction and a tris-chelate complex [Cd(H2biim)3]2(SiF6)(BF4)2 · 6EtOH was isolated. The [Cd(H2biim)3]2+ and SiF62- ions define an extended hydrogen-bonded network, in which BF4-ions surrounded by disordered ethanol molecules occupy large cavities. The two free N–H groups provide H2biim with a unique ability to form hydrogen bonds and their interactions with counter anions or other acceptors play a determining role in controlling molecular packing. The IR spectra of all compounds are discussed." @default.
• W1998921607 created "2016-06-24" @default.
• W1998921607 creator A5010237017 @default.
• W1998921607 creator A5021256006 @default.
• W1998921607 creator A5087854124 @default.
• W1998921607 date "2007-04-01" @default.
• W1998921607 modified "2023-10-02" @default.
• W1998921607 title "Synthesis, characterization and crystal structures of Cd(II) and Zn(II) complexes with 2,2′-biimidazole" @default.
• W1998921607 cites W1571847781 @default.
• W1998921607 cites W1635462970 @default.
• W1998921607 cites W1908930975 @default.
• W1998921607 cites W1973219786 @default.
• W1998921607 cites W1981463752 @default.
• W1998921607 cites W1983583654 @default.
• W1998921607 cites W1984445583 @default.
• W1998921607 cites W1987444770 @default.
• W1998921607 cites W1991215826 @default.
• W1998921607 cites W1992486067 @default.
• W1998921607 cites W2000572751 @default.
• W1998921607 cites W2000957081 @default.
• W1998921607 cites W2005561629 @default.
• W1998921607 cites W2006374795 @default.
• W1998921607 cites W2009046603 @default.
• W1998921607 cites W2012567403 @default.
• W1998921607 cites W2014577985 @default.
• W1998921607 cites W2016224533 @default.
• W1998921607 cites W2021923906 @default.
• W1998921607 cites W2023292109 @default.
• W1998921607 cites W2025983387 @default.
• W1998921607 cites W2033438891 @default.
• W1998921607 cites W2036581425 @default.
• W1998921607 cites W2037954491 @default.
• W1998921607 cites W2039070675 @default.
• W1998921607 cites W2041459768 @default.
• W1998921607 cites W2043579440 @default.
• W1998921607 cites W2047059653 @default.
• W1998921607 cites W2048213864 @default.
• W1998921607 cites W2051073838 @default.
• W1998921607 cites W2059165587 @default.
• W1998921607 cites W2060587932 @default.
• W1998921607 cites W2064469299 @default.
• W1998921607 cites W2064603714 @default.
• W1998921607 cites W2068204765 @default.
• W1998921607 cites W2071841742 @default.
• W1998921607 cites W2074465739 @default.
• W1998921607 cites W2079838254 @default.
• W1998921607 cites W2082334747 @default.
• W1998921607 cites W2086291299 @default.
• W1998921607 cites W2090492141 @default.
• W1998921607 cites W2094342954 @default.
• W1998921607 cites W2111605175 @default.
• W1998921607 cites W2128179591 @default.
• W1998921607 cites W2131233075 @default.
• W1998921607 cites W2153158193 @default.
• W1998921607 cites W2163534608 @default.
• W1998921607 cites W384454206 @default.
• W1998921607 cites W2083124959 @default.
• W1998921607 doi "https://doi.org/10.1016/j.ica.2006.09.029" @default.
• W1998921607 hasPublicationYear "2007" @default.
• W1998921607 type Work @default.
• W1998921607 sameAs 1998921607 @default.
• W1998921607 citedByCount "35" @default.
• W1998921607 countsByYear W19989216072012 @default.
• W1998921607 countsByYear W19989216072013 @default.
• W1998921607 countsByYear W19989216072014 @default.
• W1998921607 countsByYear W19989216072015 @default.
• W1998921607 countsByYear W19989216072016 @default.
• W1998921607 countsByYear W19989216072017 @default.
• W1998921607 countsByYear W19989216072018 @default.
• W1998921607 countsByYear W19989216072021 @default.
• W1998921607 crossrefType "journal-article" @default.
• W1998921607 hasAuthorship W1998921607A5010237017 @default.
• W1998921607 hasAuthorship W1998921607A5021256006 @default.
• W1998921607 hasAuthorship W1998921607A5087854124 @default.
• W1998921607 hasConcept C112887158 @default.
• W1998921607 hasConcept C115624301 @default.
• W1998921607 hasConcept C145148216 @default.
• W1998921607 hasConcept C155647269 @default.
• W1998921607 hasConcept C178516000 @default.
• W1998921607 hasConcept C178790620 @default.
• W1998921607 hasConcept C179104552 @default.
• W1998921607 hasConcept C184651966 @default.
• W1998921607 hasConcept C185592680 @default.
• W1998921607 hasConcept C197404232 @default.
• W1998921607 hasConcept C198819137 @default.
• W1998921607 hasConcept C199164860 @default.
• W1998921607 hasConcept C2779607525 @default.
• W1998921607 hasConcept C2780709120 @default.
• W1998921607 hasConcept C2780874372 @default.
• W1998921607 hasConcept C32909587 @default.
• W1998921607 hasConcept C535196362 @default.
• W1998921607 hasConcept C544153396 @default.
• W1998921607 hasConcept C544657597 @default.
• W1998921607 hasConcept C71240020 @default.
• W1998921607 hasConcept C8010536 @default.
• W1998921607 hasConceptScore W1998921607C112887158 @default.
• W1998921607 hasConceptScore W1998921607C115624301 @default.
• W1998921607 hasConceptScore W1998921607C145148216 @default.

• next