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- W1998961291 abstract "The oscillation behavior of the bromate–cerium–oxalic acid system was simulated within the FKN framework with bromine-hydrolysis control, where a radical-chain reaction of HOBr with oxalic acid and the formation of HCO2· by the reduction of Ce(IV) were assumed. When [(COOH)2]=0.03 mol dm−3 and k13=0.075 s−1 (k13: the rate constant of bromine removal), the oscillation behavior was qualitatively consistent with the experimental results. Excitability in the reduced and oxidized steady states, induced by a sudden change in the concentration of bromine, was simulated. No bistability was found. When [(COOH)2]=0.03 mol dm−3, no hysteresis near the bifurcation points was observed. However, when [(COOH)2]=0.001 mol dm−3, hysteresis was observed in the transition between the oxidized steady state and the oscillatory state." @default.
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- W1998961291 date "1988-05-01" @default.
- W1998961291 modified "2023-09-25" @default.
- W1998961291 title "A Simulation of Bromate–Cerium–Oxalic Acid Oscillations" @default.
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- W1998961291 doi "https://doi.org/10.1246/bcsj.61.1479" @default.
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