Matches in SemOpenAlex for { <https://semopenalex.org/work/W1998973555> ?p ?o ?g. }
- W1998973555 endingPage "5418" @default.
- W1998973555 startingPage "5410" @default.
- W1998973555 abstract "The rate dependence of the [Ru(η5-C5H5)(BIPHOP-F)(acetone)][Y]-catalyzed Diels−Alder reaction of cyclopentadiene with methacrolein on the anion, Y, is shown to be due to selective ion pairing. Pulsed gradient spin−echo (PGSE) diffusion measurements on the model Cp and indenyl complexes [Ru(η5-C5H5)(CH2CH-CN)(BIPHOP-F)][Y], Y = BF4 and BArF, and [Ru(η5-C9H7)(CH2CH-CN)(BIPHOP-F)][Y], Y = BF4 and BArF, respectively, combined with 1H−19F HOESY NMR data can be used to understand how the ion pairing for the BF4 anion differs relative to that of the BArF anion. Solid-state structures for [Ru(η5-C5H5)(CH2CH-CN)(BIPHOP-F)][BF4] and [Ru(η5-C5H5)(CH2CH-CN)(BIPHOP-F)][BArF] are reported and support the NMR solution data. The model carbonyl complexes [Ru(η5-C5H5)(BIPHOP-F)(CO)][Y], 8 (Y = BF4, SbF6, and BArF) have been synthesized. The IR CO stretching frequencies for 8 showed little variation with anion, thereby proving that the anions do not affect the Lewis acidity of the salts." @default.
- W1998973555 created "2016-06-24" @default.
- W1998973555 creator A5010054124 @default.
- W1998973555 creator A5014838503 @default.
- W1998973555 creator A5024683611 @default.
- W1998973555 creator A5029360555 @default.
- W1998973555 creator A5037478989 @default.
- W1998973555 creator A5045384245 @default.
- W1998973555 creator A5072837052 @default.
- W1998973555 date "2004-10-08" @default.
- W1998973555 modified "2023-10-10" @default.
- W1998973555 title "Toward an Understanding of the Anion Effect in CpRu-Based Diels−Alder Catalysts via PGSE-NMR Measurements" @default.
- W1998973555 cites W1913502283 @default.
- W1998973555 cites W1967606898 @default.
- W1998973555 cites W1968162497 @default.
- W1998973555 cites W1968289897 @default.
- W1998973555 cites W1968603155 @default.
- W1998973555 cites W1969975051 @default.
- W1998973555 cites W1976367433 @default.
- W1998973555 cites W1977738975 @default.
- W1998973555 cites W1986001811 @default.
- W1998973555 cites W1991234135 @default.
- W1998973555 cites W1994021106 @default.
- W1998973555 cites W1998406432 @default.
- W1998973555 cites W1999029703 @default.
- W1998973555 cites W2000089659 @default.
- W1998973555 cites W2004357042 @default.
- W1998973555 cites W2005827679 @default.
- W1998973555 cites W2012056354 @default.
- W1998973555 cites W2020825179 @default.
- W1998973555 cites W2026847323 @default.
- W1998973555 cites W2033093569 @default.
- W1998973555 cites W2034924813 @default.
- W1998973555 cites W2037267370 @default.
- W1998973555 cites W2039415596 @default.
- W1998973555 cites W2043968048 @default.
- W1998973555 cites W2047282411 @default.
- W1998973555 cites W2047671696 @default.
- W1998973555 cites W2049216879 @default.
- W1998973555 cites W2055874252 @default.
- W1998973555 cites W2056951386 @default.
- W1998973555 cites W2057376283 @default.
- W1998973555 cites W2058516893 @default.
- W1998973555 cites W2060458322 @default.
- W1998973555 cites W2064336303 @default.
- W1998973555 cites W2072581106 @default.
- W1998973555 cites W2073319355 @default.
- W1998973555 cites W2075558815 @default.
- W1998973555 cites W2080254302 @default.
- W1998973555 cites W2081092918 @default.
- W1998973555 cites W2083944732 @default.
- W1998973555 cites W2085960950 @default.
- W1998973555 cites W2086537505 @default.
- W1998973555 cites W2091702998 @default.
- W1998973555 cites W2092054085 @default.
- W1998973555 cites W2092892656 @default.
- W1998973555 cites W2096030987 @default.
- W1998973555 cites W2103506671 @default.
- W1998973555 cites W2124680160 @default.
- W1998973555 cites W2129811648 @default.
- W1998973555 cites W2151607320 @default.
- W1998973555 cites W2167291867 @default.
- W1998973555 cites W2170423916 @default.
- W1998973555 cites W2174745888 @default.
- W1998973555 cites W2950242185 @default.
- W1998973555 cites W2953017685 @default.
- W1998973555 cites W4210985631 @default.
- W1998973555 cites W4241182524 @default.
- W1998973555 cites W4253345956 @default.
- W1998973555 doi "https://doi.org/10.1021/om049559o" @default.
- W1998973555 hasPublicationYear "2004" @default.
- W1998973555 type Work @default.
- W1998973555 sameAs 1998973555 @default.
- W1998973555 citedByCount "60" @default.
- W1998973555 countsByYear W19989735552012 @default.
- W1998973555 countsByYear W19989735552013 @default.
- W1998973555 countsByYear W19989735552014 @default.
- W1998973555 countsByYear W19989735552015 @default.
- W1998973555 countsByYear W19989735552016 @default.
- W1998973555 countsByYear W19989735552019 @default.
- W1998973555 countsByYear W19989735552020 @default.
- W1998973555 countsByYear W19989735552021 @default.
- W1998973555 countsByYear W19989735552022 @default.
- W1998973555 countsByYear W19989735552023 @default.
- W1998973555 crossrefType "journal-article" @default.
- W1998973555 hasAuthorship W1998973555A5010054124 @default.
- W1998973555 hasAuthorship W1998973555A5014838503 @default.
- W1998973555 hasAuthorship W1998973555A5024683611 @default.
- W1998973555 hasAuthorship W1998973555A5029360555 @default.
- W1998973555 hasAuthorship W1998973555A5037478989 @default.
- W1998973555 hasAuthorship W1998973555A5045384245 @default.
- W1998973555 hasAuthorship W1998973555A5072837052 @default.
- W1998973555 hasConcept C145148216 @default.
- W1998973555 hasConcept C155647269 @default.
- W1998973555 hasConcept C161790260 @default.
- W1998973555 hasConcept C163638829 @default.
- W1998973555 hasConcept C178790620 @default.
- W1998973555 hasConcept C185592680 @default.