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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1999040344> ?p ?o ?g. }

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• W1999040344 abstract "A mathematical model has been developed to describe the disordering kinetics of a condensed monolayer adsorbed at the electrochemical interface. It is assumed that the disordering process is linked to the presence of defects in the condensed film. In the case of a perfectly smooth electrode, like a mercury drop, the only defects present in the film orginate from its formation by a 2D nucleation and growth process, so that the film can be viewed as an arrangement of linear and point defects. The model is restricted to the case where the disordering starts from lines and corresponds to the progressive shrinkage of patches having the same size. The rate of disorder propagation is considered as time dependent, this dependence being expressed as a function of the surface energy and the line tension. The expression for the surface coverage of the disordered film as a function of time is modulated by two parameters. The validation of the model is based on experimental results obtained by chronocoulometry for the disordering of a coumarin monolayer at the mercury/electrolyte interface." @default.
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• W1999040344 date "1999-02-17" @default.
• W1999040344 modified "2023-09-23" @default.
• W1999040344 title "Kinetics of Disordering of Two-Dimensional Organic Phases at the Electrochemical Interface" @default.
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• W1999040344 doi "https://doi.org/10.1021/la980945i" @default.
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