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- W1999043011 abstract "The use of a recently developed nonstationary relaxation method of measuring thermal conductivity λ of solids for monitoring crystallization kinetics of chalcogenide glasses has been analyzed. Time dependences λ(t) upon crystallization have been obtained for isothermally annealed glasses As2Se3 + 1 mol% In and the models for calculation of degree of crystallinity and evaluation of kinetic parameters of crystallization have been presented. Activation energy of crystallization, dimensionality of grain growth, and character of nucleation have been determined and the character of kinetic behavior has been discussed with consideration to possible autocatalysis of the process.Die Benutzung einer kurzlich entwickelten nichtstationaren Relaxationsmethode der Messung der thermischen Leitfahigkeit von Festkorpern zur Uberwachung der Kristallisationskinetik von Chalcogenidglasern wird analysiert. Die Zeitabhangigkeit von λ wahrend der Kristallisation wird fur isotherm getemperte As2Se3 + 1 mol% In-Glaser erhalten, und Modelle fur die Berechnung des Kristallisationsgrades und die Abschatzung der kinetischen Kristallisationsparameter werden angegeben. Die Aktivierungsenergie der Kristallisation, die Dimensionalitat des Kornwachstums und der Kernbildungscharakter werden bestimmt, und der Charakter des kinetischen Verhaltens wird unter Berucksichtigung einer moglichen Autokatalyse des Prozesses diskutiert." @default.
- W1999043011 created "2016-06-24" @default.
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- W1999043011 date "1989-09-16" @default.
- W1999043011 modified "2023-10-17" @default.
- W1999043011 title "Application of thermal conductivity measurement by the relaxation method to crystallization kinetics of glassy As2Se3 + 1 mol% In" @default.
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- W1999043011 doi "https://doi.org/10.1002/pssa.2211150113" @default.
- W1999043011 hasPublicationYear "1989" @default.
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