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- W1999046009 abstract "The solution conformation of xanthosine in liquid N2H3 has been determined by nuclear magnetic resonance. The correlation times for rotational diffusion were derived from 13C relaxation measurements. A Karplus analysis of the high-resolution spectra of the ribose moiety yields the conformation of the sugar from the H–H coupling constants. The mole fraction of the sugar in the N conformation is 0.4 at room temperature and increases slightly as the temperature decreases. From nuclear Overhauser enhancement studies, and T1 measurements of the various protons it is deduced that the N ribose is correlated with an anti conformation of the base (Y∼ 210°) while the S form of the sugar is coupled to a glycosyl torsion angle in the syn range (Y ∼ 50°–90°)." @default.
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- W1999046009 date "1974-11-01" @default.
- W1999046009 modified "2023-09-26" @default.
- W1999046009 title "A Dynamic Correlation between Ribose Conformation and Glycosyl Torsion Angle of Dissolved Xanthosine Studied by Continuous-Wave-Mode and Pulsed Nuclear-Magnetic-Resonance Methods" @default.
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- W1999046009 doi "https://doi.org/10.1111/j.1432-1033.1974.tb03819.x" @default.
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