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- W1999047615 abstract "Isothermal-thermogravimetric analyses were used to obtain kinetic data on the CFx decomposition. Weight of samplevs. time curves were obtained for compounds having stoichiometries CF0,61, CF0.96, CF1.08, and CF1.12 for several different temperatures over the range 450–650° and in both a nitrogen atmosphere and in vacuum. A small percentage of fluorine in the atmosphere was shown to strongly inhibit thermal decomposition. These experimental results were fit to various theoretical models and it was found that a satisfactory fit was obtained by use of the Avrami equation, -In(1−α)=(kt)n, where α is the extent of reaction,k is an apparent rate constant, andn is an apparent reaction order. The valuen=2.0 was indicated which corresponds to planar growth of the decomposed phase. This information was combined with analytical data for the gaseous and solid products of decomposition to formulate a detailed mechanism." @default.
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- W1999047615 date "1977-04-01" @default.
- W1999047615 modified "2023-10-14" @default.
- W1999047615 title "A study of thermal decomposition of the solid-layered fluorocarbon, poly(carbon monofluoride)" @default.
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- W1999047615 doi "https://doi.org/10.1007/bf01909964" @default.
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