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• W1999100919 abstract "In this study, electrochemical, electrochromic and spectroelectrochemical properties of a tert-butylcalix[4]arene bridged bis double-decker lutetium(III) phthalocyanine (Lu2Pc4 2) were investigated explicitly as compared with a tert-butylcalix[4]arene bridged dimeric lutetium(III) phthalocyanine [Lu2Pc2(OAc)2 1]. Distinctive differences between electrochemical and electrochromic properties of 1 and 2 were detected. Moreover, the properties of 1 and 2 were compared with previously reported S4(CH2)4 bridged Lu2Pc2(OAc)2 and Lu2Pc4. The calixarene bridged phthalocyanine (Pc) compounds, 1 and 2 showed well-defined electrochromic behaviour with green-blue and blue-purple colour transitions. The enhanced electrochromic properties of 2, as compared to 1, were attributed to its double-decker structure, probably allowing the formation of suitable ion channels for the counter ion movement in the solid film." @default.
• W1999100919 created "2016-06-24" @default.
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• W1999100919 date "2007-11-01" @default.
• W1999100919 modified "2023-10-18" @default.
• W1999100919 title "Electrochemistry and spectroelectrochemistry of tert-butylcalix[4]arene bridged bis double-decker lutetium(III) phthalocyanine, Lu2Pc4 and dimeric lutetium(III) phthalocyanine, Lu2Pc2(OAc)2" @default.
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• W1999100919 doi "https://doi.org/10.1016/j.chemphys.2007.09.005" @default.
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