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• W1999103601 abstract "The reactions of Li2PdCl4 and Na2PtCl4 with pyridine-2-carbaldehyde thiosemicarbazone, HPyTsc, afforded the complexes [Pd(PyTsc)Cl], [Pd(PyTsc)2] and [Pt(PyTsc)Cl], [Pt(PyTsc)2]. The new complexes have been characterized by elemental analyses and spectroscopic studies. A crystal structure of [Pd(PyTsc)Cl] shows that the anion of PyTsc coordinates in a planar conformation to the central palladium(II) through the pyridyl N, azomethine N and thiolato S atoms. The planar molecules are linked into polymeric chains by N–H··N and N–H··S hydrogen bonding. The protonation constants of the ligand, Ka1 and Ka2, were determined by spectrophotometry and the logarithms of their values were found to be equal to 11.58±0.05 and 3.94±0.02 respectively. Correlation of the antitumor activity of these complexes to the structure and to reduction potential is reported. The compounds [Pt(PyTsc)2] and [Pd(PyTsc)2] were found to exhibit the higher in vivo antitumor activity and the lower cytotoxicity." @default.
• W1999103601 created "2016-06-24" @default.
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• W1999103601 date "1999-02-01" @default.
• W1999103601 modified "2023-10-16" @default.
• W1999103601 title "Palladium(II) and platinum(II) complexes of pyridine-2-carbaldehyde thiosemicarbazone with potential biological activity. Synthesis, structure and spectral properties. Extended network via hydrogen bond linkages of [Pd(PyTsc)Cl]" @default.
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• W1999103601 doi "https://doi.org/10.1016/s0277-5387(98)00386-6" @default.
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