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- W1999118051 abstract "Abstract The novel reagents formed by combination of allylmagnesium chloride and a strong non‐nucleophilic lithium base (LiNR 2 ) convert non‐ or slowly enolizable carboxylic esters or carboxamides into 2‐propenyl ketones which are protected from further reaction by their in situ conversion into enolates. This modified Grignard reaction is applied to efficient syntheses of α‐damascone, β‐damascone, β‐damascenone, and various other ( E )‐1‐propenyl ketones." @default.
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- W1999118051 date "1986-02-05" @default.
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- W1999118051 title "Synthesis of (E)-1-Propenyl Ketones from Carboxylic Esters and Carboxamides by Use of Mixed Organolithium-Magnesium Reagents. Synthesis of ?-Damascone, ?-Damascone, and ?-Damascenone" @default.
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- W1999118051 doi "https://doi.org/10.1002/hlca.19860690127" @default.
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