FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1999125533> ?p ?o ?g. }

• W1999125533 endingPage "6555" @default.
• W1999125533 startingPage "6555" @default.
• W1999125533 abstract "The reaction of [8,8-(PPh(3))(2)-nido-8,7-RhSB(9)H(10)] (1) with PR(3) in a 1:2 ratio affords mixtures that contain the mono-substituted bis-PR(3)-ligated rhodathiaboranes [8,8-(PPh(3))(L)-nido-8,7-RhSB(9)H(10)] [L = PMe(2)Ph (5), PMe(3) (6)] and the corresponding tris-PR(3)-ligated compounds [8,8,8-(L)(3)-nido-8,7-RhSB(9)H(10)] [L = PMe(2)Ph (7), PMe(3) (8)]. These latter species are more conveniently prepared from the reaction of 1 with three equivalents of the monodentate phosphines, PMe(2)Ph and PMe(3). Reaction between 1 and PMePh(2) in a 1:2 ratio yields the disubstituted rhodathiaborane [8,8-(PMePh(2))(2)-nido-8,7-RhSB(9)H(10)] (4), whereas the use of three equivalents of phosphine leads to the formation of B-ligated eleven-vertex [8,8,8-(PMePh(2))(2)(H)-nido-8,7-RhSB(9)H(9)-9-(PMePh(2))] (9). Compounds 4-9 have been characterized by NMR spectroscopy, and the structures of 8 and 9 confirmed by X-ray diffraction analyses. The characterization of the cluster compounds has been aided by the use of DFT calculations on some of the species. Variable-temperature NMR studies have demonstrated a lability of the PMePh(2) ligands in compounds 4 and 9, providing mechanistic insights about the ligand substitutional chemistry in these eleven-vertex rhodathiaboranes." @default.
• W1999125533 created "2016-06-24" @default.
• W1999125533 creator A5002042279 @default.
• W1999125533 creator A5004952595 @default.
• W1999125533 creator A5009944115 @default.
• W1999125533 creator A5031601984 @default.
• W1999125533 creator A5070508830 @default.
• W1999125533 creator A5075898630 @default.
• W1999125533 creator A5080850021 @default.
• W1999125533 date "2011-01-01" @default.
• W1999125533 modified "2023-10-16" @default.
• W1999125533 title "Chemistry of 11-vertex rhodathiaboranes: reactions with monodentate phosphines" @default.
• W1999125533 cites W1980974470 @default.
• W1999125533 cites W1982846215 @default.
• W1999125533 cites W1996697207 @default.
• W1999125533 cites W2003884030 @default.
• W1999125533 cites W2006509949 @default.
• W1999125533 cites W2009046603 @default.
• W1999125533 cites W2013276048 @default.
• W1999125533 cites W2034290032 @default.
• W1999125533 cites W2085727903 @default.
• W1999125533 cites W2089612790 @default.
• W1999125533 cites W2090240586 @default.
• W1999125533 cites W2092127932 @default.
• W1999125533 cites W2131267323 @default.
• W1999125533 cites W2131350133 @default.
• W1999125533 cites W2144332006 @default.
• W1999125533 cites W2161439758 @default.
• W1999125533 cites W2166689829 @default.
• W1999125533 cites W2215836672 @default.
• W1999125533 cites W289596596 @default.
• W1999125533 cites W947635323 @default.
• W1999125533 doi "https://doi.org/10.1039/c1dt10355e" @default.
• W1999125533 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21607280" @default.
• W1999125533 hasPublicationYear "2011" @default.
• W1999125533 type Work @default.
• W1999125533 sameAs 1999125533 @default.
• W1999125533 citedByCount "14" @default.
• W1999125533 countsByYear W19991255332012 @default.
• W1999125533 countsByYear W19991255332014 @default.
• W1999125533 countsByYear W19991255332015 @default.
• W1999125533 countsByYear W19991255332016 @default.
• W1999125533 countsByYear W19991255332017 @default.
• W1999125533 countsByYear W19991255332022 @default.
• W1999125533 crossrefType "journal-article" @default.
• W1999125533 hasAuthorship W1999125533A5002042279 @default.
• W1999125533 hasAuthorship W1999125533A5004952595 @default.
• W1999125533 hasAuthorship W1999125533A5009944115 @default.
• W1999125533 hasAuthorship W1999125533A5031601984 @default.
• W1999125533 hasAuthorship W1999125533A5070508830 @default.
• W1999125533 hasAuthorship W1999125533A5075898630 @default.
• W1999125533 hasAuthorship W1999125533A5080850021 @default.
• W1999125533 hasBestOaLocation W19991255332 @default.
• W1999125533 hasConcept C115624301 @default.
• W1999125533 hasConcept C116569031 @default.
• W1999125533 hasConcept C149997192 @default.
• W1999125533 hasConcept C155647269 @default.
• W1999125533 hasConcept C161790260 @default.
• W1999125533 hasConcept C170493617 @default.
• W1999125533 hasConcept C178516000 @default.
• W1999125533 hasConcept C178790620 @default.
• W1999125533 hasConcept C185592680 @default.
• W1999125533 hasConcept C2777716191 @default.
• W1999125533 hasConcept C55493867 @default.
• W1999125533 hasConcept C66974803 @default.
• W1999125533 hasConcept C71240020 @default.
• W1999125533 hasConcept C8010536 @default.
• W1999125533 hasConceptScore W1999125533C115624301 @default.
• W1999125533 hasConceptScore W1999125533C116569031 @default.
• W1999125533 hasConceptScore W1999125533C149997192 @default.
• W1999125533 hasConceptScore W1999125533C155647269 @default.
• W1999125533 hasConceptScore W1999125533C161790260 @default.
• W1999125533 hasConceptScore W1999125533C170493617 @default.
• W1999125533 hasConceptScore W1999125533C178516000 @default.
• W1999125533 hasConceptScore W1999125533C178790620 @default.
• W1999125533 hasConceptScore W1999125533C185592680 @default.
• W1999125533 hasConceptScore W1999125533C2777716191 @default.
• W1999125533 hasConceptScore W1999125533C55493867 @default.
• W1999125533 hasConceptScore W1999125533C66974803 @default.
• W1999125533 hasConceptScore W1999125533C71240020 @default.
• W1999125533 hasConceptScore W1999125533C8010536 @default.
• W1999125533 hasIssue "24" @default.
• W1999125533 hasLocation W19991255331 @default.
• W1999125533 hasLocation W19991255332 @default.
• W1999125533 hasLocation W19991255333 @default.
• W1999125533 hasOpenAccess W1999125533 @default.
• W1999125533 hasPrimaryLocation W19991255331 @default.
• W1999125533 hasRelatedWork W1975791273 @default.
• W1999125533 hasRelatedWork W1990331428 @default.
• W1999125533 hasRelatedWork W2002933644 @default.
• W1999125533 hasRelatedWork W2010942658 @default.
• W1999125533 hasRelatedWork W2061821041 @default.
• W1999125533 hasRelatedWork W2110692098 @default.
• W1999125533 hasRelatedWork W2149469070 @default.
• W1999125533 hasRelatedWork W2952408798 @default.
• W1999125533 hasRelatedWork W4232022301 @default.
• W1999125533 hasRelatedWork W2950780349 @default.
• W1999125533 hasVolume "40" @default.

• next