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• W1999128510 abstract "—N-retinylidene-butyl-l-aminium tetrafluoroborate (NRBH+BF4-) was used to determine the frequencies of the free (non-hydrogen-bonded) v(N+-H) and v(C=NH+) vibrations and their anharmon-icity constants. For this purpose the Fourier-transform IR and near-IR (overtone) spectra were recorded. The visible-UV spectra were also taken. The results locate the free v(N+-H) band at about 3250 ± 50 cm-1; the vibration has normal anharmonicity while v(C=NH+) is very nearly harmonic. The UV and IR spectra show that the Schiff base is protonated, but that the proton is only very weakly hydrogen-bonded to the anion. Therefore, in this respect, NRBH+BF4- is a good model for the hydrogen-bonding environment of the region around the nitrogen of rhodopsin chromophores." @default.
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• W1999128510 date "2008-06-28" @default.
• W1999128510 modified "2023-10-01" @default.
• W1999128510 title "SPECTROSCOPIC STUDIES ON A RETINYLIDENE-IMINE-TETRAFLUOROBORATE" @default.
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• W1999128510 doi "https://doi.org/10.1111/j.1751-1097.1995.tb09161.x" @default.
• W1999128510 hasPublicationYear "2008" @default.
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