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- W1999146554 abstract "Ar ion-induced chemical effect on MoO 3 , Bi 2 O 3 , and β-Bi 2 O 3 ·2MoO 3 has been studied by ESCA. It was found that the reduction behavior of Mo(VI) and Bi(III) in the complex oxide is quite different from that in the single oxides. A relative oxygen enrichment of the ion-bombarded and reduced surface was observed. It has been shown that the oxygen on the bombarded surface is in a special chemical state and incapable of reoxidizing the reduced low valent metal ion. But, exposing to air leads to the reoxidation of the reduced surface and leaves the lattice oxygen anion as the only surface oxygen species. The reduction behavior of β-Bi 2 O 3 ·2MoO 3 under Ar ion bombardment seems to be similar to its redox behavior in butene catalytic oxidation. It was suggested that both of them should reflect the effect of crystal structure on the redox potential of the oxides." @default.
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- W1999146554 title "XPS study of ion-induced chemical effect on β-bismuth molybdate catalyst" @default.
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- W1999146554 doi "https://doi.org/10.1016/0169-4332(85)90219-3" @default.
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