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• W1999167130 abstract "SU-8 has gained widespread acceptance as a negative photoresist. It is also finding increasing use as a structural material in microanalytical devices. Consequently, methods to tailor the surface properties of SU-8 as well as to micropattern coatings on the surface of SU-8 are needed. The SU-8 photoresist consists of EPON SU-8 resin mixed with the photoacid generator triarylsulfonium hexafluoroantimonate. This photoacid generator can also serve as a photoinitiator generating free radicals when illuminated with UV light. Under the appropriate conditions, sufficient triarylsulfonium hexafluoroantimonate remains within cured SU-8 to act as a source of free radicals and initiate UV-mediated grafting of polymers onto the surface of the SU-8. UV-mediated grafting was used to coat SU-8 surfaces with poly(acrylic acid) and other water-soluble monomers. The SU-8 surface was chemically micropatterned by placing a mask between the UV light and SU-8. The X−Y spatial resolution of micropatterned poly(acrylic acid) on the SU-8 surface was 2 μm. Three applications of these chemically modified SU-8 surfaces were demonstrated. In the first, poly(ethylene glycol) was used to protect the SU-8 from interactions with proteins, yielding a surface resistant to biofouling. In the second demonstration, the SU-8 surface was micropatterned with a cell-resistant layer to guide cellular attachment and growth. In the final application, SU-8 micropallets were encoded with polymer lines. The bar codes were read by either absorbance or fluorescence measurements. Thus, UV-mediated graft polymerization is an efficient and effective method to micropattern coatings onto the surface of SU-8." @default.
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• W1999167130 date "2006-02-18" @default.
• W1999167130 modified "2023-10-16" @default.
• W1999167130 title "Simple Photografting Method to Chemically Modify and Micropattern the Surface of SU-8 Photoresist" @default.
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• W1999167130 doi "https://doi.org/10.1021/la053188e" @default.
• W1999167130 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16519474" @default.
• W1999167130 hasPublicationYear "2006" @default.
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