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- W1999244689 abstract "Direct C(3) alkenylation of non-aromatic enamides through palladium(II)-catalyzed Fujiwara–Moritani cross-coupling was developed. The reaction scope includes a range of cyclic enamides as well as activated alkenes. The utility of this methodology is illustrated by the synthesis of octa- or tetrahydroquinoline cores obtained from conjugated enamides via Diels–Alder cycloaddition. L’alcénylation directe en C(3) d’énamides non aromatiques a été développée selon le couplage croisé catalysé par le palladium(II) décrit par Fujiwara–Moritani. Le potentiel de cette réaction s’étend sur une large gamme d’énamides cycliques ainsi que différents alcènes activés. L’intérêt de cette méthodologie est illustrée par la synthèse de noyaux octa- ou tétrahydroquinoléine via une réaction de cycloaddition de Diels–Alder à partir d’énamides conjugués précédemment obtenus." @default.
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- W1999244689 date "2013-04-01" @default.
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- W1999244689 title "Direct alkenylation of non-aromatic enamides via palladium-catalyzed oxidative coupling: Synthetic developments and applications" @default.
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- W1999244689 doi "https://doi.org/10.1016/j.crci.2013.02.007" @default.
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