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- W1999296537 abstract "A novel disulfide-containing aniline, 1,4-dihydrobenzo[d][1,2]dithiin-5-ylamin (1), was synthesized by the alkylbromination of 1,2-dimethyl-3-nitrobenzene, followed by the formation of a disulfide bond via thioesterification and then the reduction of the nitro group. The monomer showed a reductive and oxidative potential of the disulfide bond at −0.63 and 1.25 V (vs Ag/Ag+), respectively. Although the monomer showed the oxidative potential of aniline at 0.85 V (vs SCE), the electro- or chemical-oxidative polymerization of the monomer resulted in the formation of only the oligomer, suggesting that the disulfide-containing condensed ring would prevent further propagation of the polymerization due to steric hindrance. However, the nearly ideal copolymerization of 1 with aniline (An) was carried out by chemical oxidative polymerization. The resulting copolymers (1/An = 1/1 and 2/1, by mole) had weight-averaged molecular weights (M̄w) of 10 000 and 6600, respectively, and good redox activities coupled with those of the polyaniline and disulfide group. The copolymer showed conductivities of 5.1 × 10-2 S/cm for 1/1 and 1.3 × 10-2 S/cm for 2/1 after being redoped with camphorsulfonic acid. It is suggested that these copolymers might be good candidates for the cathode materials of secondary polymer batteries." @default.
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- W1999296537 date "2001-03-30" @default.
- W1999296537 modified "2023-10-14" @default.
- W1999296537 title "Synthesis of Disulfide-Containing Aniline and Copolymerization with Aniline" @default.
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- W1999296537 doi "https://doi.org/10.1021/ma001802h" @default.
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