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- W1999341104 abstract "From the fresh leaves of Sophora tomentosa, three new lupin alkaloids, (−)-epilamprolobine, (+)-epilamprolobine N-oxide and 5-(3′-methoxycarbonylbutyroyl)aminomethyl-trans-quinolizidine N-oxide, have further been isolated along with (+)-matrine, (+)-matrine N-oxide, (+)-sophocarpine N-oxide, (−)-anagyrine, (−)- baptifoline, (−)-cytisine, (−)-N-methylcytisine, (−)-N-formylcytisine, (−)-N-acetylcytisine and (±)-ammodendrine. The absolute configurations of (+)-epilamprolobine N-oxide (1R:5R:6S) and (−)-epilamprolobine (5R:6S) have also been established by spectroscopic data and by comparison with synthetic (+)-epilamprolobine (5S:6R)derived from (−)-lupinine (5R:6R). (−)-Epilamprolobine is a diastereomer of (+)-lamprolobine (5R:6R) in Lamprolobium fruticosum and 5-(3′-methoxycarbonylbutyroyl) aminomethyl-trans-quinolizidine N-oxide is presumed to be an artefact. A biosynthetic pathway for the formation of (−)-epilamprolobine is also proposed." @default.
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- W1999341104 date "1981-01-01" @default.
- W1999341104 modified "2023-10-18" @default.
- W1999341104 title "(−)-Epilamprolobine and its N-oxide, lupin alkaloids from Sophora tomentosa" @default.
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- W1999341104 doi "https://doi.org/10.1016/s0031-9422(00)98564-9" @default.
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