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- W1999367031 abstract "The complexity of solutions of titanium(IV) and fluoride ions has been investigated in a constant ionic medium (3 M C104−) at 25° by means of potentiometric titrations with a quinhydrone electrode. The complex formation is entirely mononuclear and the highest complex is found to be TiOF42−. All equilibrium constants have been calculated with the exception of TiOF+, the the formation constant of which cannot be found by hydrogen ion measurements. The following equilibrium constants were found: TiOF+ + F− ⇄ TiOF2log β1 = 4,35 M−1TiOF+ + 2F− ⇄ TiOF3−log β2 = 8,31 M−2TiOF+ + 3F− ⇄ TiOF4−log β3 = 12,03 M−3" @default.
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- W1999367031 date "1960-09-01" @default.
- W1999367031 modified "2023-09-26" @default.
- W1999367031 title "Complexity of titanium(IV) fluoride solutions" @default.
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- W1999367031 doi "https://doi.org/10.1016/0022-1902(60)80019-x" @default.
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