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- W1999399286 endingPage "435" @default.
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- W1999399286 abstract "The lithium compound (S)-7, formed by deprotonation of the (S)-S-1-phenylethyl thiocarbamate (S)-10, is configurationally stable at −70 °C. Even at elevated temperatures it racemizes only very slowly. It represents the first essentially enantiopure α-thiocarbanion derivative and can be utilized in asymmetric synthesis. Most electrophiles (except proton acids) add to (S)-7 with complete stereoinversion. Cleavage of the substitution products leads to practically enantiopure, tertiary 1-phenylalkanethiols." @default.
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- W1999399286 date "2001-01-19" @default.
- W1999399286 modified "2023-10-16" @default.
- W1999399286 title "The Configurational Stability of an Enantioenrichedα-Thiobenzyllithium Derivative and the Stereochemical Course of Its Electrophilic Substitution Reactions; Synthesis of Enantiomerically Pure, Tertiary Benzylic Thiols[1,2]" @default.
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- W1999399286 doi "https://doi.org/10.1002/1521-3765(20010119)7:2<423::aid-chem423>3.0.co;2-y" @default.
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