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- W1999409112 abstract "The rate constant of the reaction CF3 + O2 + M → CF3O2 + M has been measured as a function of temperature in the fall-off region between 1 and 10 Torr, by laser photolysis and time-resolved mass spectrometry. The values of the fall-off parameters measured at room temperature are in good agreement with previous values and the temperature dependence of k1(0) is reasonably well accounted for by the theoretical analysis proposed by Troe and co-workers. With M = N2k1(0) = (1.9 ± 0.2) × 10−29 (T/298)(−4.7 ± 0.4) cm6 molecule−2 s−1. Reliable values of k1(∞) cannot be derived from these low pressure measurements. The rate expression proposed, k1(∞) = (9 ± 2) X 10−12 (T/298)(0±1) cm3 molecule−1 s−1, is consistent with a “broadening parameter” of the form Fc = exp(−T/395) and previous values reported at room temperature." @default.
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- W1999409112 date "1986-09-01" @default.
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- W1999409112 title "Kinetics of the reaction of CF3 with O2 over the temperature range 233–373 K" @default.
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- W1999409112 doi "https://doi.org/10.1016/0009-2614(86)80224-x" @default.
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