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- W1999456439 abstract "The pressure-induced phase transition from a neutral regular stack to an ionic dimerized stack (NR-ID) in the tetrathiafulvalene chloranil charge-transfer crystal has been studied by Raman spectroscopy. An accurate estimate of the change of ionicity during the phase transition is obtained from calculations of mode frequencies which are based on the trimer (NR phase) and dimer (ID phase) models of the electron--molecular-vibration interaction. The possibility of the formation of ionic dimers embedded in neutral chains as precursors of the phase change is discussed." @default.
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- W1999456439 date "1988-07-15" @default.
- W1999456439 modified "2023-10-16" @default.
- W1999456439 title "Raman study of the pressure-induced neutral-to-ionic transition in tetrathiafulvalene chloranil" @default.
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- W1999456439 doi "https://doi.org/10.1103/physrevb.38.1456" @default.
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