FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1999461391> ?p ?o ?g. }

• W1999461391 endingPage "424" @default.
• W1999461391 startingPage "411" @default.
• W1999461391 abstract "The axial water ligand substitution reaction on the head-to-head (HH) and head-to-tail (HT) amidato-bridged cis-diammineplatinum(III) binuclear complexes, HH- and HT-[Pt2(NH3)4(m-amidato)2(OH2)2]4+ (amidato = α-pyridonato, a-pyrrolidonato, or pivalamidato), with halide ions (X = Cl ,Br ) in acidic aqueous solution reveals a consecutive 2-step kinetics under the pseudo first-order conditions of a large excess concentration of halide ion relative to that of the complex (Cx bCpt), corresponding to formation of the monohalo (step 1) and the dihalo complexes (step 2). The first substitution step of all the HH and HT diaqua dimers consists of two parallel reaction pathways: one is the simple substituion path of one of the coordinated aqua ligands with X, and the other is the replacement in the aquahydroxo complex which is the conjugate base of the diaqua dimer. In step 2, there are three reaction pathway patterns: the direct substitution path, the path via a coordinatively unsaturated intermediate, and the unusual path of OH replacement. Step 2 proceeds via either one or two paths of the three depending on the nature of the halide ion as well as the bridging ligand. On the other hand, the substitution reaction of the hydrogenphosphato-bridged lantern-type complex, [Pt2(m-HPO4)4(OH2)2]2 proceeds in 1-step at Cx bCpt, in which the first aqua ligand substitution to form the monohalo species is rate-determining and the monohalo species is in rapid equilibrium with the dihalo complex. The rate-determining step consists of parallel pathways similar to step 1 in the amidato-bridged complex systems." @default.
• W1999461391 created "2016-06-24" @default.
• W1999461391 creator A5017653473 @default.
• W1999461391 creator A5062818098 @default.
• W1999461391 creator A5064026914 @default.
• W1999461391 date "2006-01-01" @default.
• W1999461391 modified "2023-10-11" @default.
• W1999461391 title "Kinetics and mechanisms of the axial ligand substitution reactions of platinum(III) binuclear complexes with halide ions" @default.
• W1999461391 cites W1585563747 @default.
• W1999461391 cites W1966523157 @default.
• W1999461391 cites W1969277120 @default.
• W1999461391 cites W1969428446 @default.
• W1999461391 cites W1973730612 @default.
• W1999461391 cites W1986844380 @default.
• W1999461391 cites W1987421126 @default.
• W1999461391 cites W1995998839 @default.
• W1999461391 cites W1997443897 @default.
• W1999461391 cites W1997748611 @default.
• W1999461391 cites W2000553343 @default.
• W1999461391 cites W2002056784 @default.
• W1999461391 cites W2003200810 @default.
• W1999461391 cites W2015774027 @default.
• W1999461391 cites W2018127602 @default.
• W1999461391 cites W2019807372 @default.
• W1999461391 cites W2026125067 @default.
• W1999461391 cites W2028522116 @default.
• W1999461391 cites W2031351708 @default.
• W1999461391 cites W2033938391 @default.
• W1999461391 cites W2034830151 @default.
• W1999461391 cites W2041904243 @default.
• W1999461391 cites W2042416032 @default.
• W1999461391 cites W2045469302 @default.
• W1999461391 cites W2056413946 @default.
• W1999461391 cites W2056838138 @default.
• W1999461391 cites W2056936829 @default.
• W1999461391 cites W2060270846 @default.
• W1999461391 cites W2063890383 @default.
• W1999461391 cites W2067933337 @default.
• W1999461391 cites W2070992084 @default.
• W1999461391 cites W2072285470 @default.
• W1999461391 cites W2078710024 @default.
• W1999461391 cites W2082286191 @default.
• W1999461391 cites W2087413608 @default.
• W1999461391 cites W2087467340 @default.
• W1999461391 cites W2091303806 @default.
• W1999461391 cites W2092358004 @default.
• W1999461391 cites W2095290206 @default.
• W1999461391 cites W2171656282 @default.
• W1999461391 cites W2400543097 @default.
• W1999461391 cites W2951440459 @default.
• W1999461391 cites W3004763152 @default.
• W1999461391 cites W3137268303 @default.
• W1999461391 cites W618157826 @default.
• W1999461391 doi "https://doi.org/10.1016/j.stam.2006.04.005" @default.
• W1999461391 hasPublicationYear "2006" @default.
• W1999461391 type Work @default.
• W1999461391 sameAs 1999461391 @default.
• W1999461391 citedByCount "10" @default.
• W1999461391 countsByYear W19994613912012 @default.
• W1999461391 countsByYear W19994613912013 @default.
• W1999461391 countsByYear W19994613912014 @default.
• W1999461391 countsByYear W19994613912015 @default.
• W1999461391 countsByYear W19994613912017 @default.
• W1999461391 countsByYear W19994613912018 @default.
• W1999461391 countsByYear W19994613912019 @default.
• W1999461391 countsByYear W19994613912020 @default.
• W1999461391 crossrefType "journal-article" @default.
• W1999461391 hasAuthorship W1999461391A5017653473 @default.
• W1999461391 hasAuthorship W1999461391A5062818098 @default.
• W1999461391 hasAuthorship W1999461391A5064026914 @default.
• W1999461391 hasBestOaLocation W19994613911 @default.
• W1999461391 hasConcept C111185830 @default.
• W1999461391 hasConcept C116569031 @default.
• W1999461391 hasConcept C145148216 @default.
• W1999461391 hasConcept C147789679 @default.
• W1999461391 hasConcept C155647269 @default.
• W1999461391 hasConcept C161790260 @default.
• W1999461391 hasConcept C170493617 @default.
• W1999461391 hasConcept C171560689 @default.
• W1999461391 hasConcept C178790620 @default.
• W1999461391 hasConcept C179104552 @default.
• W1999461391 hasConcept C184651966 @default.
• W1999461391 hasConcept C185592680 @default.
• W1999461391 hasConcept C2779546866 @default.
• W1999461391 hasConcept C518104683 @default.
• W1999461391 hasConcept C55493867 @default.
• W1999461391 hasConcept C71240020 @default.
• W1999461391 hasConcept C8010536 @default.
• W1999461391 hasConceptScore W1999461391C111185830 @default.
• W1999461391 hasConceptScore W1999461391C116569031 @default.
• W1999461391 hasConceptScore W1999461391C145148216 @default.
• W1999461391 hasConceptScore W1999461391C147789679 @default.
• W1999461391 hasConceptScore W1999461391C155647269 @default.
• W1999461391 hasConceptScore W1999461391C161790260 @default.
• W1999461391 hasConceptScore W1999461391C170493617 @default.
• W1999461391 hasConceptScore W1999461391C171560689 @default.
• W1999461391 hasConceptScore W1999461391C178790620 @default.
• W1999461391 hasConceptScore W1999461391C179104552 @default.

• next