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- W1999461555 abstract "Abstract 109Ag relaxation time measurements are performed on 1 m aqueous AgNO3 solutions using specially developed steady-state techniques. The basic relaxation mechanisms responsible for the longitudinal relaxation time T1 and for the transverse relaxation time T2, as well as additional mechanisms contributing in particular to T2, are discussed. A series of two types of experiments serves to determine both T1 and T2, as functions of the time elapsed since preparation of the sample, for the “transient phase” as well as for the “final state” that the sample assumes after a period of 200 to 300 hours. The present investigations exclude dipole-dipole interaction of the 109Ag nuclei with the protons of the water and with the paramagnetic O2 in the solvent as dominant relaxation mechanisms. Rather, rapid chemical exchange processes in the solvation shell of the Ag+ ion and chemical-shift anisotropy of this solvate complex are the main responsible mechanisms. Adsorption of the silver ions to colloidal silver particles presents an additional transverse relaxation mechanism. A striking correlation between this additional transverse relaxation rate and the intensity of the Rayleigh scattered light is demonstrated." @default.
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- W1999461555 date "1986-06-01" @default.
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- W1999461555 title "Longitudinal and transverse 109Ag relaxation of the silver ion in aqueous solution" @default.
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- W1999461555 doi "https://doi.org/10.1016/0022-2364(86)90323-9" @default.
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