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- W1999463492 abstract "New Sc(III) chloro-complexes [ScCl2(NNCp)(THF)] (1), [ScCl2(NNO)(THF)] (2) and [ScCl2(NNHO)(THF)] (3) {NNCp = 6-cyclopentadienylmethyl-pyridin-2-ylmethylene)-(2,6-diisopropyl-phenyl)-amine; NNO = 2-tert-butyl-6-((quinolin-8-ylimino)methyl)phenolate); NNHO = 2-tert-butyl-6-((quinolin-8-ylamino)methyl)phenolate} have been synthesized and characterized by NMR and mass spectrometry. The comparative results of the catalytic behavior of these scandium complexes towards ethylene and butadiene polymerization are reported and explained on the basis of the electronic and steric properties of the ancillary ligands." @default.
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- W1999463492 date "2008-05-01" @default.
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- W1999463492 title "Scandium complexes with [N,N,Cp] and [N,N,O] donor-set ancillary ligands as catalysts in olefin polymerization" @default.
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- W1999463492 doi "https://doi.org/10.1016/j.molcata.2008.03.009" @default.
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