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• W1999472506 abstract "Ruthenium oxide/ruthenocyanide (ruthenium oxide/hexacyanoruthenate, or mvRuO/RuCN) and iron(III) ruthenocyanide (ruthenium purple, or RP) hybrid films have been prepared using consecutive cyclic voltammetry, and the deposition process and the films' electrocatalytic properties in electrolytes containing and have been investigated. The hybrid ruthenium oxide/ruthenocyanide and RP films showed four obvious and separated redox couples with formal potentials between −0.2 and 1.0 V in monovalent cation aqueous solutions of or The cyclic voltammograms recorded the deposition of the hybrid films directly from the mixing of and ions in aqueous or cation solutions. An electrochemical quartz crystal microbalance and cyclic voltammetry were used to study the growth mechanism of the hybrid films. The electrochemical properties of the films indicate that the redox process was confined to the immobilized and mixed ruthenium oxide/ruthenocyanide and RP films. The electrocatalytic reduction properties of and by the hybrid films were also determined, as well as the electrocatalytic properties of dopamine and epinephrine. The electrocatalytic reactions of the hybrid films were investigated using the rotating ring-disk electrode method. © 2004 The Electrochemical Society. All rights reserved." @default.
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• W1999472506 creator A5091852986 @default.
• W1999472506 date "2004-01-01" @default.
• W1999472506 modified "2023-10-16" @default.
• W1999472506 title "Preparation, Characterization, and Electrocatalytic Properties of mvRuO/RuCN and RP Hybrid Film–Modified Electrodes" @default.
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• W1999472506 doi "https://doi.org/10.1149/1.1666189" @default.
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