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• W1999476786 abstract "The charge-stripping mass spectra of the ten C5H10 isomers and of cyclopropane and propene have been re-evaluated. Oxygen is the preferred collision gas for the former group and helium for the latter pair. A con bined study of the low-energy mass spectra, charge-stripping mass spectra and appearance energy measurements had to the conclusion that loss of H2O from ionized pentan-1-ol and loss of HCl from ionized 1-chloropentane both predominantly produce ionized ethylcyclopropane as the fragment ion. For the alcohol, a 1,4-elimination followed by an energetically favoured 1,2-H shift is involved, whereas for the halide a direct 1,3-elimination obtains." @default.
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• W1999476786 date "1990-07-01" @default.
• W1999476786 modified "2023-10-17" @default.
• W1999476786 title "Assigning structures to isomeric [C5H10]+ ions: The generation of ionized ethylcyclopropane from pentan-1-ol and 1-chloropentane" @default.
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• W1999476786 doi "https://doi.org/10.1002/oms.1210250707" @default.
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