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- W1999491370 abstract "Five new complexes, [(NH3)5Co(dicarboxylate)Co(NH3)5]X4 (dicarboxylate=oxalate, succinate, pimelate, fumarate, and maleate; X=ClO4− or Cl−), were synthesized by the reactions of [Co(hydrogen dicarboxylate)(NH3)5](ClO4)2 with [Co(NH3)5(H2O)](ClO4)3 and characterized by chromatographic behavior and electronic and NMR techniques. When maleate was used as the dicarboxylate, the formation of [(NH3)5Co(fumarate)Co(NH3)5]4+ as well as [(NH3)5Co(maleate)Co(NH3)5]4+ was observed. The IR and Raman spectra of [(NH3)5Co(oxalate)Co(NH3)5]4+ indicate that the symmetry of the oxalate ion in the complex may be approximated by D2h." @default.
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- W1999491370 date "1981-06-01" @default.
- W1999491370 modified "2023-09-26" @default.
- W1999491370 title "Syntheses and Characterizations of μ-Dicarboxylato-bis[pentaamminecobalt(III)] Complexes" @default.
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- W1999491370 doi "https://doi.org/10.1246/bcsj.54.1736" @default.
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