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- W1999594551 abstract "The investigation of the optical and magnetic properties of the rare earth ions in wide band gap fluoride dielectric crystals could trigger a new variety of applications using high excited electronic states. By applying laser-induced fluorescence spectroscopy in the vacuum ultraviolet (VUV) region of the spectrum (100–200 nm), it was found strong emission in the VUV and UV spectral regions due to the strong dipole 4fn−15d→4fn interconfigurational transitions of rare earth (RE) ions in wide band gap fluoride crystals. The emitted radiation is highly directional suggesting a strong paramagnetic response of the 4fn−15d electronic configuration following VUV laser excitation at 157 nm. In addition, the concentration of the Pr3+ and Tm3+ ions in KY3F10 and CaF2 crystal hosts can be accurately evaluated by measuring the magnetic moment of the Pr3+ and Tm3+ ions, using the vibrating sample magnetometer method, in a non-destructive way for the first time to our knowledge. Since the efficiency of the laser crystals doped with trivalent RE ions depends on the degree of the homogeneous distribution of the concentration of the trivalent RE ions over the crystal volume, the method can be used to evaluate the quality of the laser crystals." @default.
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- W1999594551 date "2003-12-01" @default.
- W1999594551 modified "2023-10-18" @default.
- W1999594551 title "Magnetic and optical properties of single 4fn and mixed 4fn−15d electronic configurations of trivalent rare earth ions in wide band gap dielectric crystals" @default.
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- W1999594551 doi "https://doi.org/10.1016/s0304-8853(03)00351-2" @default.
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