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• W1999615093 abstract "Gellan gum, the extracellular polysaccharide produced by Pseudomonas elodea, had been shown to be composed of a repeating, partially acetylated tetrasaccharide. Through the use of selective solvolysis of the rhamnosyl linkages in the polysaccharide with anhydrous, liquid hydrogen fluoride at −40°, oligosaccharides representing the repeating unit of the polymer in various acylated forms have now been generated. By a combination of n.m.r. spectroscopy, f.a.b.-mass spectrometry, and gas-liquid chromatographic analysis, these oligomers were shown to be substituted mainly with l-glyceric esters on O-2 of what was the 3-linked d-glucose in the original polymer, and substituted to a lesser degree with an acetic ester at O-6 of the same residue. The native gum must have the following structure." @default.
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• W1999615093 date "1986-11-01" @default.
• W1999615093 modified "2023-10-08" @default.
• W1999615093 title "Identification and location of l-glycerate, an unusual acyl substituent in gellan gum" @default.
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• W1999615093 doi "https://doi.org/10.1016/s0008-6215(00)90109-5" @default.
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