FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1999632425> ?p ?o ?g. }

• W1999632425 endingPage "114" @default.
• W1999632425 startingPage "108" @default.
• W1999632425 abstract "Transient absorption spectra following ionization of supercritical CO2 have been investigated using the pulse radiolysis technique. Absorption spectra measured from 400 to 800 nm suggest that at least two transient species absorb. We have previously reported that one species is (CO2)2+. In the near UV region, we observed a transient species of which the lifetime and reactivity are different from the dimer cation. We assign this species to a dimer anion, (CO2)2-, or an anion−molecule complex, (CO2-)(CO2)x. Comparison with the photobleaching of CO2 anion clusters in solid rare gas matrixes and their reactivity with H2 and O2 confirm the assignment. Theoretical calculations, in which solvation is taken into account, are consistent with these assignments. It is well-established that the adiabatic electron affinity of CO2 is negative, but the adiabatic electron affinity of CO2 dimer has been calculated to be 0.89 eV for D2d symmetry (CO2)2- in the gas phase. The calculations predict that CO2- in a model continuum solvent is stable to autodetachment." @default.
• W1999632425 created "2016-06-24" @default.
• W1999632425 creator A5019390430 @default.
• W1999632425 creator A5029574458 @default.
• W1999632425 creator A5059064910 @default.
• W1999632425 creator A5073746518 @default.
• W1999632425 creator A5076169995 @default.
• W1999632425 date "2001-12-05" @default.
• W1999632425 modified "2023-10-17" @default.
• W1999632425 title "Transient Negative Species in Supercritical Carbon Dioxide: Electronic Spectra and Reactions of CO₂ Anion Clusters" @default.
• W1999632425 cites W129519314 @default.
• W1999632425 cites W1601505572 @default.
• W1999632425 cites W1626272155 @default.
• W1999632425 cites W1649883212 @default.
• W1999632425 cites W1653142833 @default.
• W1999632425 cites W193705585 @default.
• W1999632425 cites W1967156722 @default.
• W1999632425 cites W1968297104 @default.
• W1999632425 cites W1974204042 @default.
• W1999632425 cites W1976561311 @default.
• W1999632425 cites W1977088562 @default.
• W1999632425 cites W1979890104 @default.
• W1999632425 cites W1980171932 @default.
• W1999632425 cites W1983555826 @default.
• W1999632425 cites W1985034369 @default.
• W1999632425 cites W1988496464 @default.
• W1999632425 cites W1990069709 @default.
• W1999632425 cites W1991365148 @default.
• W1999632425 cites W1992602375 @default.
• W1999632425 cites W1993858039 @default.
• W1999632425 cites W2002314422 @default.
• W1999632425 cites W200901497 @default.
• W1999632425 cites W2013040925 @default.
• W1999632425 cites W2013628730 @default.
• W1999632425 cites W2016156635 @default.
• W1999632425 cites W2016698046 @default.
• W1999632425 cites W2023028199 @default.
• W1999632425 cites W2025850738 @default.
• W1999632425 cites W2027152953 @default.
• W1999632425 cites W2027157035 @default.
• W1999632425 cites W2029795631 @default.
• W1999632425 cites W2032538554 @default.
• W1999632425 cites W2034315054 @default.
• W1999632425 cites W2045373754 @default.
• W1999632425 cites W2046832516 @default.
• W1999632425 cites W2047344317 @default.
• W1999632425 cites W2056217470 @default.
• W1999632425 cites W2058443670 @default.
• W1999632425 cites W2060153390 @default.
• W1999632425 cites W2060211817 @default.
• W1999632425 cites W2062210497 @default.
• W1999632425 cites W2064725445 @default.
• W1999632425 cites W2072600860 @default.
• W1999632425 cites W2081296795 @default.
• W1999632425 cites W2085366154 @default.
• W1999632425 cites W2086804631 @default.
• W1999632425 cites W2089130624 @default.
• W1999632425 cites W2092408897 @default.
• W1999632425 cites W2093817626 @default.
• W1999632425 cites W2161010521 @default.
• W1999632425 cites W2240161541 @default.
• W1999632425 cites W240584058 @default.
• W1999632425 cites W2409938079 @default.
• W1999632425 cites W2616428924 @default.
• W1999632425 cites W2619574656 @default.
• W1999632425 cites W2746988722 @default.
• W1999632425 cites W2917987242 @default.
• W1999632425 cites W4236668952 @default.
• W1999632425 cites W53560038 @default.
• W1999632425 doi "https://doi.org/10.1021/jp012340s" @default.
• W1999632425 hasPublicationYear "2001" @default.
• W1999632425 type Work @default.
• W1999632425 sameAs 1999632425 @default.
• W1999632425 citedByCount "21" @default.
• W1999632425 countsByYear W19996324252012 @default.
• W1999632425 countsByYear W19996324252014 @default.
• W1999632425 countsByYear W19996324252015 @default.
• W1999632425 countsByYear W19996324252017 @default.
• W1999632425 countsByYear W19996324252018 @default.
• W1999632425 countsByYear W19996324252019 @default.
• W1999632425 crossrefType "journal-article" @default.
• W1999632425 hasAuthorship W1999632425A5019390430 @default.
• W1999632425 hasAuthorship W1999632425A5029574458 @default.
• W1999632425 hasAuthorship W1999632425A5059064910 @default.
• W1999632425 hasAuthorship W1999632425A5073746518 @default.
• W1999632425 hasAuthorship W1999632425A5076169995 @default.
• W1999632425 hasConcept C113196181 @default.
• W1999632425 hasConcept C118419359 @default.
• W1999632425 hasConcept C121332964 @default.
• W1999632425 hasConcept C142724271 @default.
• W1999632425 hasConcept C145148216 @default.
• W1999632425 hasConcept C147789679 @default.
• W1999632425 hasConcept C148093993 @default.
• W1999632425 hasConcept C178790620 @default.
• W1999632425 hasConcept C184651966 @default.
• W1999632425 hasConcept C185592680 @default.
• W1999632425 hasConcept C198291218 @default.
• W1999632425 hasConcept C204787440 @default.

• next