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- W1999667079 abstract "Toluene diisocyanate (TDI) reacts with 2-hydroxyethyl acrylate (HEA) during the synthesis of some urethane acrylate oligomers. The present work deals with kinetic studies of the uncatalyzed bulk reaction of TDI with this monoalcohol. Back-titration and 1H -NMR in combination with HPLC are used to follow the reaction and allow a complete description of the system. The global reaction rate as well as those of each individual isocyanate group are well described by a second-order equation. Kinetic constants were calculated using the software SIMULBATCH®. The rates of the different isocyanate groups, which characterize their selectivity, are compared and the model developed in the present study allows for a good prediction of the product structure and a better control of the polymerization process and the end-use properties as well. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 75: 705–712, 2000" @default.
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- W1999667079 date "2000-01-31" @default.
- W1999667079 modified "2023-10-18" @default.
- W1999667079 title "Modeling and simulation of urethane acrylates synthesis. I. Kinetics of uncatalyzed reaction of toluene diisocyanate with a monoalcohol" @default.
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- W1999667079 doi "https://doi.org/10.1002/(sici)1097-4628(20000131)75:5<705::aid-app13>3.0.co;2-h" @default.
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