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- W1999718999 abstract "Anthraphos (trans-9,10-dihydro-9,10-ethanoanthracene-11, 12-bis(diphenylphosphine) (3), a conformationally rigid, C2-symmetric diphosphine, has been prepared in three steps, the key step being the Diels-Alder reaction between anthracene and ethyndiylbis(diphenylphosphine oxide). Resolution of anthraphos followed by formation of the [Rh(COD)(anthraphos)]BF4 complex afforded an optically active hydrogenation catalyst precursor whose crystal and molecular structure and absolute configuration were determined by single crystal X-ray diffractometry. Use of the (R,R)-(−) form of the catalyst precursor to hydrogenate (Z)-α-acetamidocinnamic acid gave (S)-(+)-N-acetylphenylalanine in 90% enantiomeric excess." @default.
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- W1999718999 date "1994-10-01" @default.
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- W1999718999 title "The synthesis of anthraphos, a conformationally rigid, C2-symmetric diphosphine and the x-ray crystal structure of [Rh(COD)(anthraphos)]BF4" @default.
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- W1999718999 doi "https://doi.org/10.1016/s0040-4039(00)78351-1" @default.
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